用原子吸收光谱法测定试液中的Pb,准确移取50mL试液2份,用铅空心阴极灯在波长283.3nm处,测得一份试液的吸光度为0.325,在另一份试液中加入浓度为50.0mg/L铅标准溶液300L,测得吸光度为0.670。计算试液中铅的质量浓度(g/L)为多少?
正确答案:
0.325=Kρx
0.670=K{(ρx×50+50×0.300)/(50+0.300)}
解出方程得
ρx=0.279mg/L
或
ρx=Ax/(A-Ax)×ρs
=0.325/(0.670-0.325)×(50.0×0.3)/50.3=0.281mg/L
0.670=K{(ρx×50+50×0.300)/(50+0.300)}
解出方程得
ρx=0.279mg/L
或
ρx=Ax/(A-Ax)×ρs
=0.325/(0.670-0.325)×(50.0×0.3)/50.3=0.281mg/L
答案解析:有
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